Infrared Spectrum of the Fundamental Vibratlon - Rotation Band of ' E - OH +
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چکیده
tween steady and oscillatory states, and marked sensitivity to stirring rate. Thiocyanate shows none of these features. A mechanistic explanation of the chlorite-bromide oscillations seems within reach given the reactions's similarity to the chlorite-iodide reaction and the success of numerical simulations' ' , 1 2 of batch behavior in the chlorite-bromide system. In contrast, very little is known about the C102--SCNreaction. We did not perform direct experiments to establish its stoichiometry, but by analogy with the bromate-thiocyanate reaction" Br03+ SCN+ H 2 0 = Br+ CN+ Sod2+ 2H+ (1)
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